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Compost Pile Monitoring Using Different Approaches:GC-MS, E-nose and dynamic olfactometry

机译:使用不同方法监测堆肥:GC-MS,电子鼻和动态嗅觉法

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摘要

The evaluation of odour emissions associated to the composting process is complex because these emissions depend on several factors such as the raw material to be composted, the different stages of the composting process, meteorological conditions, and others.For this reason, the aim of this paper is to compare complementary approaches to monitor odours. The odour source selected for this study is green waste compost at different maturity stages. The study site is a composting facility located in the south of Belgium. The comparedapproaches were: a portable e-nose developed by the Environmental Monitoring Research team (Arlon, Belgium) to monitor odorous emissions from the composting piles; chemical analyses performed in the laboratory using a GC–MS (manufactured by Thermo) to analyse volatile organic compounds which were collected by active sampling on Tenax TA sorbent simultaneously to the in situ e-nose measurements and olfactometric measurements todetermine the odour concentration (ouE/m3) using the Odile olfactometer (Odotech). The portable e-nose was also used in the laboratory with compost odour samples collected in bags. The large numbers of data sets obtained were explored by statistical methods such as principalcomponents analysis. The results obtained highlight the advantages of monitoring the composting process with these three approaches. Each approach gives differentinformation about the composting process and the emissions generated. While the e-nose is capable of identifying some chemical family emissions and some activities such as turning steps, the GC–MS identifies each chemical compound emitted and dynamic olfactometry quantifies the odour concentration (ouE/m3) in relationship with these emissions.
机译:与堆肥过程相关的气味排放的评估很复杂,因为这些排放取决于多个因素,例如要堆肥的原材料,堆肥过程的不同阶段,气象条件等。因此,此目的本文旨在比较监测气味的补充方法。这项研究选择的气味来源是处于不同成熟阶段的绿色废料堆肥。研究地点是位于比利时南部的堆肥设施。比较的方法是:由环境监测研究小组(比利时阿隆)开发的便携式电子鼻,用于监测堆肥堆中的臭味排放;在实验室中使用GC-MS(由Thermo生产)进行化学分析,以分析挥发性有机化合物,这些化合物是通过在Tenax TA吸附剂上进行主动采样而收集的,同时进行原位电子鼻测量和嗅觉测量以确定气味浓度(ouE / m3)使用Odile嗅觉计(Odotech)。便携式电子鼻也用于实验室,将堆肥气味样品收集在袋子中。通过统计方法(例如主成分分析)探索了获得的大量数据集。获得的结果突出显示了使用这三种方法监控堆肥过程的优势。每种方法都会给出有关堆肥过程和产生的排放的不同信息。电子鼻能够识别某些化学族排放物和某些活动(例如转弯步骤),而GC-MS可以识别出每种排放的化学化合物,动态嗅觉法可以量化与这些排放有关的气味浓度(ouE / m3)。

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